Dissociation of isomerization of excited C3H5 radicals in the gas phase
✍ Scribed by Jan Niedzielski; Janusz Gawłowski; Tomasz Gierczak
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 896 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The reaction of hot hydrogen atoms originating from 253.7‐ and 228.8‐nm photolyses of hydrogen sulfide with 1‐butene was investigated. Of the hydrogen atoms undergoing addition a substantial part undergoes it in a first collision (37 and 48% at 253.7 and 228.8 nm, respectively) yielding
KEYWORDS : gas phase acidities of 1,2-butadiene and 2-butyne ; heats of formation of anions ; ab initio calculations ; C 4 H 5 Fourier transform ion cyclotron resonance ; gas-phase ion/molecule reactions.
The gas phase chemistry of C3H6Br(+) cations generated via low energy electron impact on various dibromopropanes has been studied by using Fourier transform ion cyclotron resonance mass spectrometry. Neutral substrate molecules that have been selected to probe the bimolecular reactivity of the C3H6B
The rate of decomposition of 2-pentoxy radical to acetaldehyde and n-propyl radical has been studied in the presence of NO in competition with nitrite formation at and above 200 kPa pressure over the temperature range of 363-413 K. The rate coefficient for the decomposition is given as log(k,,/s-')