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Dissociation of Difluoroethylenes. II. Direct Classical Trajectory Study of the HF Elimination from 1,2-Difluoroethylene

✍ Scribed by González-Vázquez, Jesús; Martínez-Núñez, Emilio; Fernández-Ramos, Antonio; Vázquez, Saulo A.


Book ID
126334423
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
108 KB
Volume
107
Category
Article
ISSN
1089-5639

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A kinetic study of the thermal eliminati
✍ J. A. Kerr; D. M. Timlin 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 619 KB

The kinetics of the thermal elimination of H F from 1,2-difluoroethane CHzFCHzF -+ CHz=CHF + H F have been studied in a static system over the temperature range 734-820'K. was shown to be first order and homogeneous, with a rate constant of The reaction log kz(s-l) = 13.39 f 0.2 -(62.9 f 0.9)/0 wher