The coordination of a resonance-stabilized hydrocarbon cation and anion yielded a series of unprecedented hydrocarbons, which are susceptible to thermal heterolytic cleavage of carbon-carbon s bonds in polar media, generating the original ions under reversible conditions. When the component ions wer
✦ LIBER ✦
Dissociation energies of axial and equatorial carbon—carbon bonds in substituted decahydroquinolols
✍ Scribed by V.G. Zaikin; N.S. Wulfson
- Book ID
- 104245929
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 146 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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## Abstract Collision induced dissociation of the carbon cage compounds cubane, kepone and mirex breaks the cage structures. The energy available for bond breaking is thus not less than about 9 eV, and the time between energy acquisition and subsequent unimolecular fragmentation is long enough that