Dissociation energies and excitation levels of alkaline-earth oxides
โ Scribed by Tj. Hollander; P.J. Kalff; C.Th.J. Alkemade
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 245 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0022-4073
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๐ SIMILAR VOLUMES
Cluster model wavefunctions for the alkaline-earth oxides are analyzed to determine the origin of the trend of the chemical shifts of the binding energies, BEs, of the metal core levels. Two cancelling initial states mechanisms in the oxides are responsible for the trend. One is the increase of the
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Solubility products of various alkaline-earth oxides in NaCI-KC1 at IOOOK have been determined potentiometrically by use of a calcia stabilized zirconia PO'-indicator electrode. The corresponding pK, values (in molality scale) for MgO. CaO and BaO, (respectively 9.0 f 0.15, 5.0 + 0.3,2.31 + 0.05) ar