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Dissociation and aromatization of a semibenzene. Reactions of triphenylmethyl and methyl isobutyryl radicals

✍ Scribed by Engel, Paul S.; Chen, Yanqiu; Wang, Chengrong

Book ID: 127094966
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 922 KB
Volume: 56
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00009a028

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## Abstract The Hg(6^3^__P__~1~) photosensitized decompositions of 3‐methyl‐1‐butene, 2‐methyl‐2‐butene, 3,3‐dimethyl‐1‐butene, and 2,3‐dimethyl‐1‐butene have been used to generate 1‐methylallyl, 1,2‐dimethylallyl, 1,1‐dimethylallyl, and 1,1,2‐trimethylallyl radicals in the gas phase at 24 ± 1°C. F