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Disproportionation of trimethylsilyl radicals to a sila olefin in the liquid phase

✍ Scribed by Cornett, Becky J.; Choo, Kwang Yul; Gaspar, Peter P.


Book ID
127030520
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
281 KB
Volume
102
Category
Article
ISSN
0002-7863

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Disproportionation-combination ratios of
✍ W. E. Falconer; W. A. Sunder πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 659 KB

Disproportionation-combination ratios have been obtained for small alkyl radicals produced in the mercury-photosensitized hydrogenation of ethylene, propylene, butene-1, butene-2, and isobutene. For conditions favoring thermalized radicals, kd/k, (ethyl, ethyl) = 0.14, kd/k, (isopropyl, isopropyl) =