Disproportionation-combination ratios of
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W. E. Falconer; W. A. Sunder
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Article
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1971
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John Wiley and Sons
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English
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Disproportionation-combination ratios have been obtained for small alkyl radicals produced in the mercury-photosensitized hydrogenation of ethylene, propylene, butene-1, butene-2, and isobutene. For conditions favoring thermalized radicals, kd/k, (ethyl, ethyl) = 0.14, kd/k, (isopropyl, isopropyl) =