Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdot.SO2).cntdot.SO2 and Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-SSO3)

✍ Scribed by Toupadakis, Andreas; Kubas, Gregory J.; Burns, Carol J.

• Book ID: 118174387
• Publisher: American Chemical Society
• Year: 1992
• Tongue: English
• Weight: 1023 KB
• Volume: 31
• Category: Article
• ISSN: 0020-1669
• DOI: 10.1021/ic00044a025