Disproportionation and Methylation of Toluene with Methanol Over Zeolite Catalysts
โ Scribed by A. Baduraig; T. Odedairo; S. Al-Khattaf
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 305 KB
- Volume
- 53
- Category
- Article
- ISSN
- 1022-5528
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The liquid phase benzoylation of toluene with benzoyl chloride (BOC) has been studied over ZSM-12, beta, mordenite, Y and REY zeolites and \(\mathrm{AlCl}_{3}\) at \(383 \mathrm{~K}\). Zeolite \(\mathrm{H}\)-beta is more active and selective than the other zeolites. \(\mathrm{H}-\mathrm{ZSM}-5, \mat
Various mordenites, viz. the hydrogen, sodium, alkaline earth and lanthanum forms, have been used as catalysts for the conversion of ethylbenzene in a micro-reactor. High reaction temperatures (~> 573 K) were required for cation exchanged non-dealuminated mordenites to overcome mass transfer limitat