A simple variation method is employed to obtain an expression for the dispersion interaction of closed-shell atoms in term of sum rule properties of the dynamic multipole polarizabilities of the interacting atoms. An analytical es&e&on for the dispersion cocfficicnts for the interaction of hydrogen
β¦ LIBER β¦
Dispersion interaction between helium atoms
β Scribed by R. Luyckx; Ph. Coulon; H.N.W. Lekkerkerker
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 231 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Accurate values for the coefficients of the Re6 R-' and R-lo in the series representation of the dispersion interaction between two heIium atoms at distance R are obtaied by a simpIe variation method.
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The relation between the variation-perturbation method and sum rule methods is explored. Thevariation-perturbation method is a simple method which yields accurate numerical results for all higher-order multipole dispersion coefficients. T&is method is related to a method which obtains bounds on dis