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Dispersion and Exfoliation of Graphene in Rubber by an Ultrasonically-Assisted Latex Mixing and In situ Reduction Process

✍ Scribed by Yanhu Zhan; Jinkui Wu; Hesheng Xia; Ning Yan; Guoxia Fei; Guiping Yuan


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
963 KB
Volume
296
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

NR/GE composites were prepared by an ultrasonically‐assisted latex mixing and in situ reduction process. Graphene oxide was dispersed in NRL using an ultrasonic field and was then reduced in situ, followed by latex coagulation to obtain the NR/GE masterbatch. The results show that the process produces a much better dispersion and exfoliation of GE in the matrix and contributes to an increase in the tensile strength compared to conventional direct mixing. Compared to pure rubber, the tensile strength and tear strength for NR/(2 wt.‐%)GE composites were increased by ≈47 and 50%, respectively. With increasing GE content, the maximum torque, crosslink density, elastic modulus, and thermal conductivity of NR/GE composites were found to increase. magnified image