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Discrimination in Metal-Ion Binding to RNA Dinucleotides with a Non-Bridging Oxygen or Sulfur in the Phosphate Diester Link

✍ Scribed by Bernd Knobloch; Barbara Nawrot; Andrzej Okruszek; Roland K. O. Sigel


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
60 KB
Volume
14
Category
Article
ISSN
0947-6539

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Discrimination in Metal-Ion Binding to R
✍ Bernd Knobloch; Barbara Nawrot; Andrzej Okruszek; Roland K. O. Sigel 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 382 KB

## Abstract Replacement of a non‐bridging oxygen in the phosphate diester bond by a sulfur has become quite popular in nucleic acid research and is often used as a probe, for example, in ribozymes, where the normally essential Mg^2+^ is partly replaced by a thiophilic metal ion to reactivate the sy