Discreteness-of-charge effects in electr
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W.R. Fawcett; S. Levine
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Article
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1973
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Elsevier Science
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The classical theory of simple electrode processes predicts that the rate of electron transfer depends on the electrochemical potentials of the reactant and product 1. Since these species are present in the vicinity of a charged interface, the electrostatic potential experienced by the reactant at t