Discotic liquid crystals of transition metal complexes 27: supramolecular structure of liquid crystalline octakisalkylthiophthalocyanines and their copper complexes
โ Scribed by Ban, Kazue; Nishizawa, Kaoru; Ohta, Kazuchika; Shirai, Hirofusa
- Book ID
- 120927546
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 343 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0959-9428
- DOI
- 10.1039/B000134L
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An unidentified mesophase D ~x~ of bis(octakisdodecyloxyphthalocyaninato)lutetium(III) reported by us in 1997 was reinvestigated by temperature-dependent X-ray diffraction and temperature-dependent electronic spectra of the thin film. The D ~x~ phase was thus established as a novel type of D ~r
Five novel long-chain-substituted porphyrin derivatives, tetrakis(3,4-dialkylphenyl)porphyrins (abbreviated as (C n ) 8 TPPH 2 (n = 8, 12, 18), (C 18 ) 8 TPPCu and (C 18 ) 8 TPPNi), were synthesized and their mesomorphism was investigated. It was found that the (C n ) 8 TPPH 2 (n = 8, 12), derivativ