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Dirhodium(II) Tetrakis(perfluorobutyrate)-Catalyzed 1,4-Hydrosilylation of α,β-Unsaturated Carbonyl Compounds.

✍ Scribed by Masahiro Anada; Masahiko Tanaka; Kanami Suzuki; Hisanori Nambu; Shunichi Hashimoto


Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Enrico Nieddu; Maurizio Cataldo; Francesco Pinna; Giorgio Strukul 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Acetalization of α,β-Unsaturated Carbonyl Compounds Catalyzed by Complexes of Pt(II). -Cationic diphosphine complexes of Pt(II) are sufficiently Lewis acidic to catalyze the acetalization of α,β-unsaturated carbonyl compounds (I) with ethylene glycol. In all cases tested, the Pt-complex displays co