Dirhodium tetraacylate complexes and monovalent ligands. Adduct formation in solution as monitored by NMR spectroscopy

Phenylselenenylalkanes, their adducts wi

Phenylselenenylalkanes, their adducts with the dirhodium complex Rh2(MTPA)4 and ligand exchange mechanisms in solution as studied by 1H, 13C and 77Se NMR spectroscopy

✍ Shahid Malik; Stefan Moeller; Gábor Tóth; Tamás Gáti; Muhammad Iqbal Choudhary; 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB

## Abstract Twelve secondary phenylselenenylalkanes and ‐cycloalkanes were studied by ^1^H, ^13^C and ^77^Se NMR spectroscopy in the presence of the chiral dirhodium complex Rh~2~[(__R__)‐MTPA]~4~ [Rh–Rh; MTPA‐H = (__R__)‐(+)‐methoxytrifluoromethylphenylacetic acid, Mosher's acid]. The 1 : 1 and 2