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Directivity of the intramolecular O→Si bond in pentacoordinate organosilicone compounds

✍ Scribed by T. N. Aksamentova; N. N. Chipanina; M. G. Voronkov; O. M. Trofimova; E. A. Zelbst; V. K. Turchaninov

Book ID
111460316
Publisher
Springer
Year
2009
Tongue
English
Weight
233 KB
Volume
79
Category
Article
ISSN
1070-3632

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✍ R.K. Harris; B.J. Kimber 📂 Article 📅 1976 🏛 Elsevier Science ⚖ 446 KB

Silicon-29 spin-lattice relaxation times and 29Si-(1H} nuclear Overhauser enhancements are reported for five trialkylsilanes and for sym-tetramethyldisiloxane, all of which contain a direct Si-H bond. Relaxation rate contributions from (Si, H) dipolar interactions and from other mechanisms are evalu