Directional Solidification and Melting of Eutectic GaIn

✍ Scribed by J. N. Koster

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 360 KB
• Volume: 34
• Category: Article
• ISSN: 0232-1300
• DOI: 10.1002/(sici)1521-4079(199911)34:9<1129::aid-crat1129>3.0.co;2-p

✦ Synopsis

Eutectic gallium-indium is studied in a horizontal Bridgman furnace geometry. Differential temperature gradients are applied to solidify and melt the alloy while observing in-situ the interface morphology and the chemical segregation in the melt and in the solid as well. Upon cooling, a wedge-type indiumrich mushy zone develops at the cold wall. The melt is initially stirred by convective flow. After solidification starts the roll cell recedes to be replaced by a chemically layered conductive melt that eventually solidifies with rather uniform eutectic structure. Upon re-melting, the morphology of the interface adopts a profile that is predetermined by the original solid structure. Those patterns, as well as the flow, are different from single element solid melting experiments and have yet to be modeled. Under high thermal gradient the convective flow mixes the binary melt and the visualized density pattern eventually becomes that of a homogeneous melt.