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Directed regiochemical control in the ring expansion reactions of a substituted trans-decalone

✍ Scribed by Jeffrey Aubé; Marlys Hammond

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
273 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

A derivative of the Wieland-Miescher ketone can selectively be converted into either regioisomeric ring-expanded lactam. The synthesis of the diastereomeric N-a-methylbenzyl oxaziridine derivatives determines the regiochemistry of the product lactam and additionally allows the separation of a racemic substrate into regio-and enantioisomeric lactams.

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