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Directed Nickel-Catalyzed Negishi Cross Coupling of Alkyl Aziridines

✍ Scribed by Nielsen, Daniel K.; Huang, Chung-Yang (Dennis); Doyle, Abigail G.

Book ID
120839297
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
627 KB
Volume
135
Category
Article
ISSN
0002-7863

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Nickel-catalyzed carbonylative Negishi c
Nickel-catalyzed carbonylative Negishi cross-coupling reactions
✍ Qiaoling Wang; Chuo Chen πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 225 KB

Catalytic carbonylative Negishi cross-coupling reactions are described. This method readily provides various enones from enol triflates and diorganozinc reagents with catalytic amounts of nickel(II) chloride-4,4 0 -dimethoxyl-2,2 0 -bipyridyl under carbon monoxide atmosphere. The rate of carbon mono