๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Directed metalation of tertiary benzamides. Ortho N-aryl amination and synthesis of acridones

โœ Scribed by Iwao, M.; Reed, J. N.; Snieckus, V.

Book ID
121485455
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
350 KB
Volume
104
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Directed ortho metalations of tertiary b
Directed ortho metalations of tertiary benzamides using lactones as electrophiles
โœ Timothy J. Brenstrum; Margaret A. Brimble; Ralph J. Stevenson ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 573 KB

Absbwct : Directed onho me&lath of oxygenated terth'y benzamides using tert-butyllithium in THF / TMEDA at -78OC followed by the addition of a range of lactones afforded orfho-substituted keto-

Ortho metalation directed by ฮฑ-amino alk
Ortho metalation directed by ฮฑ-amino alkoxides. An improved synthesis of ortho-substituted aryl ketones
โœ Daniel L. Comins; Jack D. Brown ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 215 KB

Ortho-substituted aryl ketones are prepared from N-[2-(dimethylamino)ethy]-Nmethylbenzamides via ortho lithiation of intermediate a-amino alkoxides, formed in situ by addition of RLi. also described. An ortho lithiation of N-[2-(dimethylamino)ethyl]-N-methylbenzamide is Tertiary a-amino alkoxides, f