Synthesis of 3-deoxy-d-arabino-2-heptulo
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Mella Adlersberg; David B. Sprinson
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Article
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1984
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Elsevier Science
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English
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3-Deoxy-D-urubino-2-heptulosonic acid 7-phosphate (S), the first committed intermediate in aromatic amino acid biosynthesis, has been synthesized in good yield by treatment of methyl (methyl 3-deoxy-D-urubino-2-heptulopyranosid)onate with diphenylphosphoric chloride under mild conditions to give the