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Direct transformation of organosulfur compounds to organophosphorus compounds: rhodium-catalyzed synthesis of 1-alkynylphosphine sulfides and acylphosphine sulfides

✍ Scribed by Mieko Arisawa; Takuya Watanabe; Masahiko Yamaguchi

Book ID
104099017
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
399 KB
Volume
52
Category
Article
ISSN
0040-4039

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✦ Synopsis

A rhodium-catalyzed method for the synthesis of organophosphorus compounds directly from organosulfur compounds was developed. In the presence of RhH(PPh 3 ) 4 and depe, the reaction of 1-alkylthioalkynes with tetraethyldiphosphine disulfide gave 1-alkynylphosphine sulfides. The same complex catalyzed the reaction of thioesters giving acylphosphine sulfides.

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