Direct transformation of ethanol to ethyl acetate on Cu/ZrO2catalyst
โ Scribed by Lixia Wang; Wanchun Zhu; Dafang Zheng; Xue Yu; Jing Cui; Mingjun Jia; Wenxiang Zhang; Zhenlu Wang
- Publisher
- Springer-Verlag
- Year
- 2010
- Tongue
- English
- Weight
- 555 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1878-5190
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A series of 1%Pd/WO 3 -ZrO 2 catalysts with different W/Zr ratios and calcination temperatures of WO 3 -ZrO 2 were prepared by an impregnation method. Their crystal structure, surface state, and acidity were determined using X-ray diffraction, N 2 adsorption, NH 3 temperature-programmed desorption,
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Ru-, Rh-, and Pd/WO 3 -ZrO 2 catalysts were studied for the direct oxidation of ethylene to acetic acid. The catalytic activity and selectivity depended strongly on the noble metals used. Rh/WO 3 -ZrO 2 gave the highest conversion of ethylene, whereas Ru/WO 3 -ZrO 2 was almost inactive. The higher c