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Direct synthesis of α-hydroxyacetophenones through molecular iodine activation of carbon–carbon double bonds

✍ Scribed by Wu, Xia; Gao, Qinghe; Lian, Mi; Liu, Shan; Wu, Anxin


Book ID
126730150
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
509 KB
Volume
4
Category
Article
ISSN
2046-2069

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✍ Andrew Pelter; Redha Al-Bayati 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 182 KB

Butenollde anlons do not react with orthoesters and butenolldes do not react with carbocatlons derived from acetals and orthoesters However double activation of the butenollde (as the carbanlon) and the alkoxyalkanes (as the stablllsed carbocatlons) leads to high yield carbon-carbon bond formation o