Direct synthesis of organic carbonates by oxidative carboxylation of olefins catalyzed by metal oxides: developing green chemistry based on carbon dioxide

Versatile Synthesis of Pyrrole-2-acetic

Versatile Synthesis of Pyrrole-2-acetic Esters and (Pyridine-2-one)-3-acetic Amides by Palladium-Catalyzed, Carbon Dioxide-Promoted Oxidative Carbonylation of (Z)-(2-En-4-ynyl)amines

✍ Bartolo Gabriele; Giuseppe Salerno; Alessia Fazio; Lucia Veltri 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB 👁 2 views

## Abstract The oxidative carbonylation of readily available (__Z__)‐(2‐en‐4‐ynyl)amines, catalyzed by the PdI~2~‐KI system, selectively afforded in satisfactory yields (40–95 %) either pyrrole‐2‐acetic ester or (pyridine‐2‐one)‐3‐acetic amide derivatives, depending on the susbtitution pattern of t