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Direct Synthesis of Magnesium Porphine via 1-Formyldipyrromethane

โœ Scribed by Dogutan, Dilek Kiper; Ptaszek, Marcin; Lindsey, Jonathan S.

Book ID
118059405
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
82 KB
Volume
72
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis of 1-Formyldipyrromethanes.
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โœ Marcin Ptaszek; Brian E. McDowell; Jonathan S. Lindsey ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 17 KB

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Synthesis of 1-Formyldipyrromethanes
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A novel, high-yielding synthesis of meso
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A new method for the synthesis of meso-substituted porphyrins is described: reaction of 5,10,15,20-tetrabromoporphine magnesium complex with aryl or heteroaryl boronic acids in the presence of Pd(PPh 3 ) 4 gave meso-substituted porphyrins in yields up to 70%.