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Direct Synthesis of Imines via Solid State Reactions of Carbamates with Aldehydes

✍ Scribed by Lee, Byeongno; Lee, Kyu Hyung; Lim, Byung Wook; Cho, Jaeheung; Nam, Wonwoo; Hur, Nam Hwi

Book ID
120557892
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
501 KB
Category
Article
ISSN
1615-4150

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## Abstract __γ__‐Chlorocarbanions of proper nucleophilicity, generated from 3‐chloropropyl pentachlorophenyl sulfone (=pentachloro[(3‐chloropropyl)sulfonyl]benzene; **1**; Ar=C~6~Cl~5~), add to electron‐deficient formal imines **3a**–**l** to produce anionic adducts that enter intramolecular subst