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Direct synthesis of dipteran sex pheromones by the Wittig reaction in a heterogeneous medium

✍ Scribed by Le Bigot, Yves; Delmas, Michel; Gaset, Antoine


Book ID
125536311
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
426 KB
Volume
31
Category
Article
ISSN
0021-8561

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In the presence of trifluoroacetic anhydride or N-chlorosuccinimide, aliphatic aldehydes react with dimesitylboron stabilised carbanions to give, after work up, the corresponding ketones, a process which is unique among Wittig type reactions. Yields of ketones are satisfactory in all cases