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Direct Synthesis of a Mercury Salt-Carbene Complex

✍ Scribed by Prof. Dr. H.-W. Wanzlick; Dipl.-Chem. H.-J. Schönherr

Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
240 KB
Volume
7
Category
Article
ISSN
0044-8249

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Investigation of a mercury(II) carbene c
Investigation of a mercury(II) carbene complex: bis(1,3-dimethylimidazol-2-ylidene) mercury chloride
✍ Anthony J. Arduengo III; Richard L. Harlow; William J. Marshall; T. K. Prakasha 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB

## The reaction of I,3-dimethylimidazolium chloride with Hg(O,CCH,), afforded a bis(carbene)mercuty (II) complex (2), which is characterized by multinuclear N M R spectroscopy (IH, 13C, 15N, and 199Hg) and by single-crystal X-ray analysis. As a consequence of chloride-ion interaction with the mercur