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Direct synthesis of 1-organylsilatranes from organyltrichlorosilanes and tris(2-hydroxyethyl)amine

✍ Scribed by M. G. Voronkov; G. A. Kuznetsova


Book ID
111460095
Publisher
Springer
Year
2009
Tongue
English
Weight
149 KB
Volume
79
Category
Article
ISSN
1070-3632

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Metal directed stereoselective synthesis
✍ Gunda I. Georg; EyΓΌp AkgΓΌn πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 251 KB

The enolate-imine condensation of the lithio dianion 8 of ethyl 3-hydroxybutyrate 7 with Nanisylcinnamylideneimine was studied in the presence of a variety of metal salts and organometallic reagents. Addition of terr-butyl magnesium chloride to the reaction mixture produced the reZ(l'R,3R,4S)-3-(l'-