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Direct suprafacial 1,3-hydrogen migration of 1,1-dimethyl-2-(9-phenanthryl)cyclopropane

✍ Scribed by Wu Guo-Sheng; Ma Yun-Fei; Li Zhen-Lian; Xu Jian-Hua


Book ID
112058716
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
460 KB
Volume
5
Category
Article
ISSN
0256-7660

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The gas phase isomerization of 1,l -dimethyl-2-vinylcyclopropane to cis-2-methylhexa-1,4-diene has been studied in a static system. The isomerization is homogeneous and kinetically first order. The rate constants were independent of initial reactant pressure in the range 0.6 to 2 torr and of added n