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Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins

โœ Scribed by Jat, J. L.; Paudyal, M. P.; Gao, H.; Xu, Q.-L.; Yousufuddin, M.; Devarajan, D.; Ess, D. H.; Kurti, L.; Falck, J. R.

Book ID
121439302
Publisher
American Association for the Advancement of Science
Year
2014
Tongue
English
Weight
381 KB
Volume
343
Category
Article
ISSN
0036-8075

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Synthesis of N-methoxy and N-H aziridine
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โœ Edwin Vedejs; Hisroshi Sano ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 256 KB

Electron-rich alkenes me converted into N-methoxyaziridines by treatment with HN(OCH3J2 and trimethylsilyl tn#lute. Reduction with Liiammonia affords fhe N-H aziridines.