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Direct Probe of End-Segment Distribution in Tethered Polymer Chains

✍ Scribed by Basu, J. K.; Boulliard, J. C.; Capelle, B.; Daillant, J.; Guenoun, P.; Mays, J. W.; Yang, J.

Book ID: 126820008
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 590 KB
Volume: 40
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma070817d

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Dependencies of PDI on monomer conversion (a = ([M] 0 -[M])/[M] 0 ) for systems with [M] 0 /[I] 0 = 10 2 , computed for various (shown in the Figure) values of (k tr / k p ) N ([M] 0 /[I] 0 ). Dotted lines: systems without disproportionation (Ref. [1] ), circles: systems with disproportionation.