Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide over a Modified Titanium Silicalite
β Scribed by Luigi Balducci; Daniele Bianchi; Rossella Bortolo; Rino D'Aloisio; Marco Ricci; Roberto Tassinari; Raffaele Ungarelli
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 98 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
## Abstract The hydroxylation of benzene to phenol with hydrogen peroxide was investigated using different solvents and a series of catalysts, obtained by modification of titanium silicalite (TSβ1). The best results were obtained after postβsynthesis treatment of TSβ1 with NH~4~HF~2~ and H~2~O~2~.
## Abstract The efficient catalytic oxidation of secondary amines to nitrones using hydrogen peroxide as primary oxidant is described. The titanium(IV) complex **2** bearing a __C__~3~βsymmetrical triphenolate amino ligand has proved to be an airβ and waterβtolerant complex that efficiently catalyz