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Direct Organocatalytic Asymmetric Mannich-Type Reactions in Aqueous Media: One-Pot Mannich-Allylation Reactions.

✍ Scribed by Armando Cordova; Carlos F. III Barbas

Publisher
John Wiley and Sons
Year
2003
Weight
136 KB
Volume
34
Category
Article
ISSN
0931-7597

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HBF 4 -catalyzed Mannich-type reaction of silyl enolates with aldimines took place smoothly in aqueous organic solvent to afford b-aminocarbonyl compounds in high yields. The HBF 4 -catalyzed Mannich-type reaction also proceeded smoothly in water without organic solvent in the presence of a surfacta