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Direct one step mono-functionalisation of symmetrical 1,2-diols

✍ Scribed by Paul A Clarke; Robert A Holton; Nadim E Kayaleh

Book ID: 104210092
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 123 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00224-0

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✦ Synopsis

The mono-functionalisation of meso-and C 2 -symmetric diols has been achieved via the use of a new lanthanide(III) chloride catalysed acylation reaction.

📜 SIMILAR VOLUMES

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✍ Paul A. Clarke 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 59 KB

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One-Step Synthesis of Symmetrically Substituted 2,6-Bis(pyrazol-1-yl)pyridine Systems

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## Abstract A one‐pot synthetic route that allows functionalization of the 2,6‐bis(pyrazol‐1‐yl)pyridine backbone in the 4‐ and 4″‐pyrazole positions by direct H(4)‐pyrazole halogen exchange is described. The diiodo derivative in particular provides easy access to additional functionalities through