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Direct Observation of the Gas-Phase Criegee Intermediate (CH 2 OO)

โœ Scribed by Taatjes, Craig A.; Meloni, Giovanni; Selby, Talitha M.; Trevitt, Adam J.; Osborn, David L.; Percival, Carl J.; Shallcross, Dudley E.


Book ID
121705018
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
561 KB
Volume
130
Category
Article
ISSN
0002-7863

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The reactions of the Criegee intermediat
โœ Osamu Horie; Peter Neeb; Geert K. Moortgat ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 134 KB ๐Ÿ‘ 2 views

Ozonolysis of cis-and trans-2-butene isomers were carried out in a 570 l spherical glass vessel in 730 torr synthetic air at 295 ฯฎ 3 K. The initial concentrations were 5 to 10 ppmv for the isomers and 2 to 5 ppmv for ozone. Quantitative yields were determined by FTIR spectroscopy for CH 3 CHO, HCHO,