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Direct observation of the degenerate 9-methyl-9-barbaralyl cation

✍ Scribed by Ahlberg, Per.; Grutzner, John B.; Harris, David L.; Winstein, Saul.


Book ID
126053044
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
344 KB
Volume
92
Category
Article
ISSN
0002-7863

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Alkyl-9-Β―uorenyl cations and the parent 9-Β―uorenyl cation are generated via photoheterolysis of the corresponding 9-Β―uorenols within alkali metal zeolites such as LiY, NaY and Nab, and observed directly using nanosecond laser Β―ash photolysis. The observation of the highly reactive and highly unstabl