Direct Observation of Surface Intermediates Formed by Selective Oxidation of Alcohols on Silica-Supported Molybdenum Oxide
โ Scribed by Seman, M.; Kondo, J. N.; Domen, K.; Reed, C.; Oyama, S. T.
- Book ID
- 126219787
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 704 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0022-3654
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๐ SIMILAR VOLUMES
Many metal nitrates, especially zinc(I1) and copper(I1) nitrates, supported on silica gel, oxidized secondary and benzylic alcohols to the corresponding ketones and aldehydes efficiently. The supported reagent technique has received increasing attention in recent years.l As one oxidizng reagent of a
Swmnary: Potassium permanganate adsorbed on solid supports can be used to oxidize unsaturated secondary alcohols to the corresponding ketones without degradation of the carbon-carbon double bonds. The adsorption of reagents onto solid supports is known to induce changes in the reactivity and selecti