Conventional Ziegler-Natta catalysts, based on TiCl 4 supported on MgCl 2 , were modified by substituting a part of the chlorides by cyclopentadienyl (and derivatives) ligands. Although these catalysts are very active (activities up to 10 5 g PE/g catalyst/h) they exhibit a conventional Ziegler-Natt
Direct Observation of Radicals in the Activation of Ziegler–Natta Catalysts
✍ Scribed by Thomas Risse; Jörg Schmidt; Heiko Hamann; Hans-Joachim Freund
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 162 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
We are grateful to funds from the Ministerium f¸r Wissenschaft und Forschung, NRW, the Deutsche Forschungsgemeinschaft, the Max-Planck-Gesellschaft, and the Fonds der Chemischen Industrie.
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