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Direct observation of intermediate heteroexcimer in the photoinduced hydrogen-atom transfer reaction by picosecond laser spectroscopy

✍ Scribed by Tadashi Okada; Nobuyuki Tashita; Noboru Mataga


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
324 KB
Volume
75
Category
Article
ISSN
0009-2614

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✦ Synopsis


Tune-resolved absorptlon spectra of pyrene-aromatlc amme systems have been measured by picosecond laser spectroscopy. It has been confirmed that the heteroewxmer IS a real reaction mtermedlate m the photomduced hydrogen-atom transfer m the pyrene-diphenylamme system m toluene. The hfetune of the heteroewuner IS ~200 ps, III a good aDeement wth the rse time of l-hydro-1-pyrenyl radxal