𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer

✍ Scribed by Yoshiki Kubota; Masaki Takata; Ryotaro Matsuda; Ryo Kitaura; Susumu Kitagawa; Kenichi Kato; Makoto Sakata; Tatsuo C. Kobayashi

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
301 KB
Volume
117
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

Hydrogen storage is an important technology and is indispensable for the establishment of clean hydrogen energy systems. Although various materials have been studied as hydrogen-storage materials, [1] there is yet no decisive way to store and release H 2 molecules efficiently. Adsorption of H 2 molecules in metal-organic porous materials [2, 3] is one of the most promising candidates. To develop a rational synthetic strategy for novel metal-organic porous materials that can adsorb large amounts of H 2 molecules, the elucidation of the intermolecular interactions between H 2 molecules and pore walls is essential. Despite several investigations into novel metal-organic porous materials as hydrogen-storage materials, [4] little is known about the effective interaction mechanism and the fundamental structural characteristics of the adsorbed H 2 molecules. In previous work, [5] we determined the assembled structure of O 2 molecules in nanochannels by

📜 SIMILAR VOLUMES

Titelbild: Direct Observation of Hydroge
Titelbild: Direct Observation of Hydrogen Molecules Adsorbed onto a Microporous Coordination Polymer (Angew. Chem. 6/2005)
✍ Yoshiki Kubota; Masaki Takata; Ryotaro Matsuda; Ryo Kitaura; Susumu Kitagawa; Ke 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB 👁 1 views

**Grundlegende Strukturinformationen** über Wasserstoffmoleküle, die in Nanokanälen adsorbiert sind, werden für das rationale Design neuartiger metall‐organischer poröser Materialien als Wasserstoffspeicher benötigt. Das Titelbild zeigt die Ladungsdichteverteilung von Wasserstoffmolekülen in den Nan

Direct NMR Spectroscopic Observation of
Direct NMR Spectroscopic Observation of a Lanthanide-Coordinated Water Molecule whose Exchange Rate Is Dependent on the Conformation of the Complexes
✍ Silvio Aime; Alessandro Barge; Mauro Botta; Alvaro S. De Sousa; David Parker 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 83 KB 👁 1 views

A large difference in the exchange rate of the coordinated water molecule is seen in solution for the diastereoisomers M and m of a europium(III) complex with an octadentate, neutral macrocyclic ligand (k (M)<k (m)). This finding is of high relevance to the design of more efficient contrast agents f