✦ LIBER ✦

Direct observation of a cationic intermediate in the acid-catalyzed decomposition of (2-hydroxy-, (2-ethoxy-, and (2-phenoxyethyl)cobaloximes

✍ Scribed by Brown, Kenneth L.; Ramamurthy, Sheela

Book ID: 126330953
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 386 KB
Volume: 1
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00062a037

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

On the mechanism of the direct acid cata

On the mechanism of the direct acid catalyzed formation of 2,3-disubstituted imidazo[1,2-a]pyridines from 2-aminopyridines and acetophenones. Concurrence between ketimine and Ortoleva–King type reaction intermediated transformations

✍ Kurteva, Vanya B. ;Lubenov, Lubomir A. ;Antonova, Daniela V. 📂 Article 📅 2014 🏛 The Royal Society of Chemistry 🌐 English ⚖ 281 KB

Novel concepts in directed biaryl synthe

Novel concepts in directed biaryl synthesis, XXXVII. Synthesis and enantiomerization of a nonracemic 2-hydroxy-2′-biarylcarbaldehyde, a probable intermediate in the atropo-enantioselective ring opening of biaryl lactones

✍ Bringmann, Gerhard ;Hartung, Thomas 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 401 KB

## Abstract The directed preparation of a “free”, i.e. nonprotected biaryl with a phenolic OH function and a formyl group in opposite __ortho__ positions, in a nonracemic form, is described. The free activation barrier ΔG^≠^ for the atropisomerization, which was determined to be 99.2 kJ mol^−1^, is

Direct Observation by Electrospray Ioniz

Direct Observation by Electrospray Ionization Mass Spectrometry of [Cp*RhMo3O8(OMe)5]−, a Key Intermediate in the Formation of the Double-Bookshelf-Type Oxide Cluster [(Cp*Rh)2Mo6O20(OMe)2]2−

✍ Satoshi Takara; Seiji Ogo; Yoshihito Watanabe; Koji Nishikawa; Isamu Kinoshita; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 99 KB 👁 1 views

ChemInform Abstract: Reactions of Comple

ChemInform Abstract: Reactions of Complex Ligands. Part 78. [2 + 1] Cycloadditions of Diazoalkanes to Enol Ethers Catalyzed by Chromium Complexes — The First Direct Spectroscopic Observation of a Carbene Complex Intermediate.

✍ J. PFEIFFER; K. H. DOETZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

The acid-catalyzed rearrangement CH3O&#x

The acid-catalyzed rearrangement CH3O → CH2OH and its involvement in the dissociation of the methanol dimer radical cation: A Quid pro Quo reaction

✍ Peter C. Burgers; Paul J.A. Ruttink 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 253 KB

A Computational Study of the Hydroxy-Gro

A Computational Study of the Hydroxy-Group Directivity in the Peroxyformic Acid Epoxidation of the Chiral Allylic Alcohol ( Z ) - 3-Methyl-3-penten-2-ol: Control of Threo Diastereoselectivity through Allylic Strain and Hydrogen Bonding

✍ Adam, Waldemar; Bach, Robert D.; Dmitrenko, Olga; Saha-Möller, Chantu R. 📂 Article 📅 2000 🏛 American Chemical Society 🌐 English ⚖ 316 KB