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Direct N-vinylation of aryl and hetaryl carboxamides with trimethoxyvinylsilane

✍ Scribed by Pavel Arsenyan; Alla Petrenko; Sergey Belyakov

Book ID
104095575
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
259 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

A general method for direct N-vinylation of aryl and hetaryl carboxamides with trimethoxyvinylsilane using a copper(II) acetate-TBAF system as catalyst is elaborated. The yield of N-vinyl amides depends strongly on the initial amide and nature of the solvent.

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