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Direct measurement of the force between solid surfaces in a polar liquid

โœ Scribed by H.K. Christenson; R.G. Horn

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
481 KB
Volume
98
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The farce between mica sheets in a polar liquid (propybne carbonate) with various electrolyte concentrations is found to be the sum of an electrostatic double-layer force, accurately described by Gouy-Chapman theory, and a short-range osciilatory salvation force, qualitatively similar to tltat found in non-polar liquids.

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Direct mauremenb of lte salvation force belween two solid surfaces in a binary mixlure of non-polar bquids have been perrormed Addltlon of cyclohexane (rnolaular dmmeter 0 = 0.55 nm) IO ocramethylcyclo~elrasllonane (0 = 0.35 nm) causes a reduction m the rzmge or the salvation rorce and a~ equirnolar

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III\_ MEASUREMENTS IN AIR ..\_\_\_.\_\_\_\_.\_\_\_\_\_\_.\_.\_~\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_~\_~\_\_\_\_\_\_\_\_\_\_66 IV\_ KEASUREMENTS IN ELECTROLYTE SOLUTIONS .\_.

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## are dependent on the interactions between colloidal particles The van der Waals and electrostatic interaction energies beor particles and macroscopic surfaces. Traditionally, colloitween a single particle and a flat plate were measured using the dal interactions have been described by the DLVO