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Direct mass spectrometry of polymers. X. Primary thermal fragmentation processes in totally aromatic polyesters

✍ Scribed by Foti, Salvatore ;Giuffrida, Mario ;Maravigna, Pietro ;Montaudo, Giorgio

Publisher: John Wiley and Sons
Year: 1984
Weight: 699 KB
Volume: 22
Category: Article
ISSN: 0360-6376
DOI: 10.1002/pol.1984.170220601

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## Abstract The primary fragmentation processes in the thermal decomposition of polymers were studied in detail on a series of structurally related polyureas by direct pyrolysis with a mass spectrometer. Our results indicate that polyureas I–III undergo a quantitative depolycondensation process ana