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Direct liquid-phase fluorination of aromatic compounds. New advances in electrophilic fluorination

✍ Scribed by G.P. Gambaretto; L. Conte; C. Fraccaro; M. Napoli


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
43 KB
Volume
54
Category
Article
ISSN
0022-1139

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A series of new electrolytes, R,NF.mHF (R: CH,, C,H, and n-C,H,, m > 34, has been utilized for electrochemical fluorination of organic compounds. These electrolytes are non-viscous liquids at room temperature, and have high electrolytic conductivity and high electrochemical stability. The electrolys

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The formation mechanism of 1,4\_difluorobenzene (5) has been studied during the electrolyses of chlorobenzene (l), I-chloro-4-fluorobenzene (2), bromobenzene (3) and 1-bromo-4-fluorobenzene (4) in Et,NF mHF. The mechanism consists of a cathodic dehalogeno-defluorination of 3-chloro-3,6,6trifluoro-1,