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Direct Iodination of Alkanes

✍ Scribed by Montoro, Raúl; Wirth, Thomas


Book ID
111687540
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
40 KB
Volume
5
Category
Article
ISSN
1523-7060

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Direct iodination of alkanes and cycloalkanes in the presence of superelectrophiles has been accomplished for the first time. The reactions of saturated hydrocarbons with I 2 in the presence of CCl 4 •2AlI 3 at -20°C afforded monoiodides in good yields and selectivities.

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