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Direct Introduction of Deuterium into Benzene

โœ Scribed by HORIUTI, J.; POLANYI, M.


Book ID
109508891
Publisher
Nature Publishing Group
Year
1934
Tongue
English
Weight
113 KB
Volume
134
Category
Article
ISSN
0028-0836

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Direct Transformation of the Second Exci
โœ Dr. D. Bryce-Smith; Dr. A. Gilbert; Prof. D. A. Robinson ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 239 KB ๐Ÿ‘ 2 views

However, treating 2-lithiothiophene with quinoline at 20ยฐC by Giiman's methodf6] leads only to 2-(2-thienyl)quinoline (2) (38%), indicating steric hindrance of 4-addition by the peri-hydrogen atom of the quinoline. In the following reactions of the quinoline system with 2-lithiothiophene derivatives