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Direct Introduction of a Boryl Substituent into the 2-Position of Azulene: Application of the Miyaura and Smith Methods to Azulene

✍ Scribed by Kei Kurotobi; Masato Miyauchi; Katsuto Takakura; Toshihiro Murafuji; Yoshikazu Sugihara

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 90 KB
Volume: 2003
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200300001

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✦ Synopsis

Abstract

The 4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolanyl group was directly introduced into the 2‐positions of azulenes with high selectivity by the C−H activation method with use of iridium catalysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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